Beilstein J. Org. Chem.2013,9, 1319–1325, doi:10.3762/bjoc.9.148
, possessing unique structural features.
Keywords: acetyleneaddition; dichloroethylene; dimerisation; dioxanes; tetrahydrofurans; Introduction
Recently, we have shown that simple ketones reacted with 1,1-dichloroethylene, in the presence of potassium tert-butoxide, to afford rare (Z)-chloro-exo
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Graphical Abstract
Scheme 1:
Formation of (Z)-chloro-exo-methyleneketals.